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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Reactions of nitrile anions ： ウィキペディア英語版 Reactions of nitrile anions Nitrile anions are the conjugate bases of alkyl nitriles. They undergo nucleophilic addition and substitution reactions with various electrophiles.〔Arseniyadis, S.; Kyler, K. S.; Watt, D. S. ''Org. React.'' 1984, ''31'', 1-71. 〕 ==Introduction== Although nitrile anions are functionally similar to enolates, the extra pi bond in nitrile anions provides them with a unique ketene-like geometry. Additionally, deprotonated cyanohydrins can act as masked acyl anions, giving products impossible to access with enolates alone. The mechanisms of nitrile anion addition and substitution are well understood; however, strongly basic conditions are usually required, which can limit the synthetic usefulness of the reaction. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Reactions of nitrile anions」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.